Valence Bond Glass on an fcc Lattice in the Double PerovskiteBa2YMoO6

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Valence bond glass on an fcc lattice in the double Perovskite Ba2YMoO6.

We report on the unconventional magnetism in the cubic B-site ordered double perovskite Ba2YMoO6, using ac and dc magnetic susceptibility, heat capacity and muon spin rotation. No magnetic order is observed down to 2 K while the Weiss temperature is approximately -160 K. This is ascribed to the geometric frustration in the lattice of edge-sharing tetrahedra with orbitally degenerate Mo5+ s=1/2 ...

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ژورنال

عنوان ژورنال: Physical Review Letters

سال: 2010

ISSN: 0031-9007,1079-7114

DOI: 10.1103/physrevlett.104.177202